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Juliusz Warzywoda, Ph.D.

Senior Research Scientist
julow@coe.neu.edu

Education:

Ph.D., 1989, Chemical Engineering
Worcester Polytechnic Institute

B.S. / M.S., 1985, Chemical Engineering
Lodz Technical University (Poland)

Employment History:

Northeastern University, Center for Advanced Microgravity Materials Processing, Department of Chemical Engineering

2000 - present, Senior Research Scientist

Northeastern University, Center for Advanced Microgravity Materials Processing, Department of Chemical Engineering

1997 - 2000, Senior Research Associate

Worcester Polytechnic Institute, Department of Chemical Engineering

1989 - 1997, Research Associate

Research Interests:

Synthesis and characterization of zeolite and zeo-type materials
Advanced characterization methods for microporous and mesoporous materials
Experimental and theoretical aspects of zeolite nucleation and growth
Materials processing in space

Publications

Ji, Z., Warzywoda, J., and Sacco, Jr., A., "Synthesis and morphological control of large titanosilicate ETS-10 crystals," Microporours and Mesoporous Materials, 109, 1-11 (2008).

Jirapongphan, S.S., Warzywoda, J., Budil, D.E., and Sacco, Jr., A., "Enantioseparation of phenylglycinol in chiral-modified zeolite HY: A molecular simulation study," Chirality, 19, 514-517 (2007).

Jirapongphan, S.S., Warzywoda, J., Budil, D.E., and Sacco, Jr., A., "Molecular modeling of chiral-modified zeolite HY employed in enantioselective separation,"Chirality, 19, 508-513 (2007).

Jirapongphan, S.S., Warzywoda, J., Budil, D.E., and Sacco, Jr., A., "The role of sorbate in the determination of preferential adsorption sites in zeolite HY: A theoretical study,"Microporous and Mesoporous Materials, 103, 280-283 (2007).

Ji, Z., Warzywoda, J., and Sacco, Jr., A., "Titanosilicate ETS-10 thin film preparation on fused silica optical fibers," Microporous and Mesoporous Materials, 101, 279-287 (2007).

Jirapongphan, S. S., Warzywoda, J., Budil, D.E., and Sacco, Jr., A., "Simulation of benzene adsorption in zeolite HY using supercage-based docking," Microporous and Mesoporous Materials, 94, 358-363 (2006).

Yilmaz, B., Warzywoda, J., and Sacco Jr., A., "Spectroscopic characterization of the quantum wires in titanosilicates ETS-4 and ETS-10," Nanotechnology, 17, 4092-4099 (2006).

Bazzana, S., Dumrul, S., Warzywoda, J., and Sacco, Jr., A., “Low-voltage high-resolution scanning electron microscope imaging of the uncoated and Cr-coated zeolite Beta,” Microporous and Mesoporous Materials. 92, 165-172 (2006).

Yilmaz, B., Shattuck, K.G., Warzywoda, J., and Sacco, Jr., A., “Oriented growth of ETS-4 films using the method of secondary growth,” Chemistry of Materials, 18, 1107-1112 (2006).

Yilmaz, B., Shattuck, K.G., Warzywoda, J., and Sacco, Jr., A., “Controlling crystal orientation in ETS-4 films by secondary growth method,” Journal of Materials Science, 41, 3135-3138 (2006).

Mendonza, A.M., Warzywoda, J., and Sacco, Jr., A., “Investigation of structural order and morphology of MCM-41 mesoporous silica using an experimental design methodology,” Journal of Porous Materials , 13, 39-50 (2006).

Shattuck, K.G., Yilmaz, B., Warzywoda, J., and Sacco, Jr., A., “Hydrothermal synthesis of oriented ETS-4 films on porous alpha-alumina substrates,” Microporous and Mesoporous Materials , 88, 56-62 (2006).

Ji, Z., Warzywoda, J., and Sacco, Jr., A., "Competitive nucleation and growth in seeded batch crystallization of titanosilicate ETS-10 using Ti(SO4)2," Microporous and Mesoporous Materials, 81, 201-210 (2005).

Ji, Z., Yilmaz, B., Warzywoda, J., and Sacco, Jr., A., "Hydrothermal synthesis of titanosilicate ETS-10 using Ti(SO4)2," Microporous and Mesoporous Materials, 81, 1-10 (2005).

Yilmaz, B., Warzywoda, J., and Sacco Jr., A., "Synthesis of large ETS-4 crystals in the Na and Na/K systems: The effects of alkali metal ion and synthesis mixture alkalinity," Journal of Crystal Growth, 271(1-2), 325-331 (2004).

Miraglia, P. Q., Yilmaz, B., Warzywoda, J, and Sacco, Jr., A., "Surface growth mechanisms and structural faulting in the growth of large single and spherulitic titanosilicate ETS-4 crystals," Journal of Crystal Growth, 270(3-4), 674-684 (2004).

Warzywoda, J., Yilmaz, B., Miraglia, P. Q., and Sacco, Jr., A., "Characterization of titanosilicate ETS-4 crystals grown from synthesis mixtures of different alkalinity," Microporous and Mesoporous Materials, 71, 177-183 (2004).

Yilmaz, B., Miraglia, P. Q., Warzywoda, J., and Sacco, Jr., A., "Synthesis of titanosilicate ETS-4 with controlled morphology and investigation of its crystallization kinetics," Microporous and Mesoporous Materials, 71, 167-175 (2004).

Akata, B., Warzywoda, J., and Sacco, Jr., A., "Gas phase Meerwein-Ponndorf-Verley reaction: Correlation of the 3665 cm-1 IR band with the cis-alcohol selectivity," Journal of Catalysis, 222(2), 397-403 (2004).

Akata, B., Yilmaz, B., Jirapnogphan, S. S., Warzywoda, J., and Sacco, Jr., A., "Characterization of zeolite Beta grown in microgravity," Microporous and Mesoporous Materials, 71, 1-9 (2004).

Miraglia, P. Q., Yilmaz, B., Warzywoda, J., Bazzana, S., and Sacco, Jr., A., "Morphological and surface analysis of titanosilicate ETS-4 synthesized hydrothermally with organic precursors," Microporous and Mesoporous Materials, 69, 71-76 (2004).

Manning, M.P., Miller, R.P., McLaughlin, G., Sacco, A., Akata, B., Bazzana, S., Jirapongphan, S.S., Mendonza, A.M., Yilmaz, B., Warzywoda, J., and Sacco, Jr., A., "Zeolite Crystal Growth on the International Space Station," Proceedings of the 14th International Zeolite Conference, Editors: E. van Steen, L.H. Callanan and M. Claeys, ISBN: 0-958-46636-X, 147-154 (2004).

Manning, M.P., Warzywoda, J., Karahan, O., and Sacco, Jr., A., "Enantioselective adsorption of hydrobenzoin on zeolite Beta," Proceedings of the 14th International Zeolite Conference, Editors: E. van Steen, L.H. Callanan, and M. Claeys, ISBN: 0-958-46636-X, pp. 1957-1960 (2004).

Yilmaz, B., Shattuck, K.G., Miraglia, P.Q., Warzywoda, J., and Sacco, Jr., A., "Synthesis of titanosilicate ETS-4 utilizing organic precursors," Proceedings of the 14th International Zeolite Conference, Editors: E. van Steen, L.H. Callanan, and M. Claeys, ISBN: 0-958-46636-X, pp. 763-769 (2004).

Sacco, Jr., A., Warzywoda, J., Bazzana, S., and Miraglia, P., "Fundamental understanding of zeolite and zeotype growth mechanisms using AFM and SEM," Proceedings of the South African Chemical Engineering Congress, Sun City, South Africa, 3-5 September, ISBN: 0-958-46095-7 (2003).

Dumrul, S., Warzywoda, J., and Sacco, Jr., A., "Direct synthesis of ZSM-5 crystals on gold modified by zirconium-phosphonate multilayers," Impact of zeolites and other porous materials on the new technologies at the beginning of the new millenium, Proceedings of the 2nd International FEZA (Federation of the European Zeolite Associations) Conference, Taormina, Italy, September 1-5, Editors: R. Aiello, G. Giordano and F. Testa, Stud. Surf. Sci. Catal. Vol. 142, Elsevier, Amsterdam, pp. 1497-1504 (2002).

Bazzana, S., Dumrul, S., Warzywoda, J., Hsiao, L., Klass, L., Knapp, M., Rains, J.A., Stein, E.M., Sullivan, M.J., West, C.M., Woo, J.Y., and Sacco, Jr., A., "Observations of layer growth in synthetic zeolites by field emission scanning electron microscopy," Impact of zeolites and other porous materials on the new technologies at the beginning of the new millenium, Proceedings of the 2nd International FEZA (Federation of the European Zeolite Associations) Conference, Taormina, Italy, September 1-5, Editors: R. Aiello, G. Giordano and F. Testa, Stud. Surf. Sci. Catal. Vol. 142, Elsevier, Amsterdam, pp. 117-124 (2002).

Dumrul, S., Bazzana, S., Warzywoda, J., Biederman, R.R., and Sacco, Jr., A., "Imaging of crystal growth-induced fine surface features in zeolite A by atomic force microscopy," Microporous and Mesoporous Materials, 54, 79-88 (2002).

Ferchiche, S., Valcheva-Traykova, M., Vaughan, D. E. W., Warzywoda, J., and Sacco, Jr., A., "Synthesis of large single crystals of templated Y faujasite," Journal of Crystal Growth, 222, 801-805 (2001).

Ferchiche, S., Warzywoda, J., and Sacco, Jr., A., "Direct Synthesis of Zeolite Y with Large Particle Size," International Journal of Inorganic Materials, 3, 773-780 (2001).

Ferchiche, S., Warzywoda, J., and Sacco, Jr., A., "Interaction/synergistic effect of Mg2+ and Ba2+ on the size and morphology of the zeolite L crystals," Zeolites and Mesoporous Materials at the Dawn of the 21st Century, Proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July, (ed. A. Galarneau, F. Di Renzo, F. Fajula, J. Vedrine), Elsevier, Amsterdam, Stud. Surf. Sci. Catal. Vol. 135, paper 02 p17 (on CD) (2001).

Carlsson, K.A., Warzywoda, J., and Sacco, Jr., A., "Modeling of Silicalite crystallization from clear solution," Zeolites and Mesoporous Materials at the Dawn of the 21st Century, Proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July, (ed. A. Galarneau, F. Di Renzo, F. Fajula, J. Vedrine), Elsevier, Amsterdam, Stud. Surf. Sci. Catal., Vol. 135, paper 02 p16 (on CD) (2001).

Warzywoda, J., Dumrul, S., Bazzana S., and Sacco, Jr. A., "Static zeolite MCM-22 synthesis using two-level factorial design," Zeolites and Mesoporous Materials at the Dawn of the 21st Century, Proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July, (ed. A. Galarneau, F. Di Renzo, F. Fajula, J. Vedrine), Elsevier, Amsterdam, Stud. Surf. Sci. Catal., Vol. 135, paper 03 p13 (on CD) (2001).

Russell, P.C., Stuhler, S.L., Kouli, A.L., Warzywoda, J., and Sacco, Jr., A., "Synthesis of zeolite Sr,K-ZK-5," Zeolites and Mesoporous Materials at the Dawn of the 21st Century, Proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July, (ed. A. Galarneau, F. Di Renzo, F. Fajula, J. Vedrine), Elsevier, Amsterdam, Stud. Surf. Sci. Catal. Vol. 135, paper 02 p21 (on CD) (2001).

Warzywoda, J., Bac, N., Rossetti, Jr., G. A., van der Puil, Jansen, J. C., van Bekkum, H., and Sacco, Jr., A., "Synthesis of high-silica ZSM-5 in Microgravity," Microporous and Mesoporous Material, 38, 423-432 (2000).

Warzywoda, J., Bac, N., Jansen, J. C., and Sacco, Jr., A., "Growth of zeolites A and X in low earth orbit," Journal of Crystal Growth, 220, 140-149 (2000).

Warzywoda, J., Valcheva-Traykova, M., Rossetti, Jr., G. A., Bac, N., Joesten, R., Suib, S. L. and Sacco, Jr., A., "Characterization of zeolites A and X grown in low earth orbit," Journal of Crystal Growth, 220, 150-160 (2000).

Warzywoda, J., Bac, N., and Sacco, Jr., A., "Synthesis of Large Zeolite X Crystals," Journal of Crystal Growth, 204, 539-541 (1999).

Guray, I., J. Warzywoda, N. Bac, and Sacco, Jr., A., "Synthesis of Zeolite MCM-22 under Rotating and Static Conditions," Microporous and Mesoporous Materials, 31, 241-251, (1999).

Sacco, Jr., A., Bac, N., Warzywoda, J., Rossetti, Jr., G., and Valcheva-Traykova, M., "Zeolite Crystal Growth in Space," Invited Paper, Materials Research Society Symposium. Proc., Vol. 551, pp. 245-254 (1999).

Warzywoda, J., "Linde Type F", Microporous and Mesoporous Materials, 22, 590-591 (1998).

Warzywoda, J., "Barrer K-F", Microporous and Mesoporous Materials, 22, 588-589 (1998).

Bac, N., Warzywoda, J., and Sacco, Jr., A., "Experiment III: Zeolite crystal growth in microgravity - The USML-2 mission," in: Second United States Microgravity Laboratory: One Year Report, Vol.1, Editors: M. Vlasse, D. McCauley and C. Walker, August 1998, pp. 3-35 – 3-59, NASA/TM-1998-208697.

Guray, I., Marceau, M., Sacco, T.L., Whalen, L.M., Bac, N., Warzywoda, J., and Sacco, Jr., A., "Investigating the nucleation and growth of zeolite crystals in space," in: Space Technology and Applications International Forum, 3rd Conference on Commercial Development of Space, January, 1998, Albuquerque, New Mexico, USA, AIP Conference Proceedings 420.

Fulcher, M., Warzywoda, J., Sacco, Jr., A., Thompson, R.W., and Dixon, A.G., "Gel shrinkage and nutrient addition in unstirred batch zeolite A reaction systems," Microporous Materials, 10, 199-209 (1997).

Warzywoda, J., Dixon, A.G., Suib, S.L., Thompson, R.W., and Sacco, Jr., A., "The role of the dissolution of silicic acid powders in aluminosilicate synthesis mixtures in the crystallization of large mordenite crystals," Zeolites, 16, 125-137 (1996).

Sacco, Jr., A., Bac, N., Warzywoda, J., Guray, I., Thompson, R.W., and McCauley, L.A., "Zeolite crystal growth in microgravity," in: Space Technology and Applications International Forum, 1st Conference on Commercial Development of Space, January 8-11, 1996, Albuquerque, New Mexico, USA, AIP Conference Proceedings 361, Part One, Editor: M.S. El-Genk, pp. 429-432 (1996).

Warzywoda, J., Dixon, A.G., Thompson, R.W., and Sacco, Jr., A., "Synthesis and control of the size of large mordenite crystals using porous silica substrates," Journal of Materials Chemistry, 5, 1019-1025 (1995).

Sacco, Jr., A., Bac, N., Coker, E.N., Dixon, A.G., Warzywoda, J., and Thompson, R.W., "The growth of zeolites A, X and Mordenite in space," in: Joint "L+1" Science Review on USML-1 and USMP-1 with the Microgravity Measurement Group, September 22-24, 1993, Huntsville, Alabama, USA, NASA Conference Publication 3272, vol. I, pp. 447-472 (1994).

Warzywoda, J., and Thompson, R.W., "Synthesis of zeolite A in the Na/K system and the effect of seeding," Zeolites, 11, 577-582 (1991).

Warzywoda, J., Edelman, R.D., and Thompson, R.W., "Crystallization of high silica ZSM-5 in the presence of seeds," Zeolites, 11, 318-324 (1991).

Edelman, R.D., Kudalkar, D.V., Ong, T.J., Warzywoda, J., and Thompson, R.W., "Crystallization phenomena in seeded zeolite syntheses," Zeolites, 9, 496-502 (1989).

Warzywoda, J., and Thompson, R.W., "Analysis of zeolite crystallization with autocatalytic nucleation," Zeolites, 9, 341-345 (1989).

Warzywoda, J., and Thompson, R.W., "Analysis of zeolite crystallization with autocatalytic nucleation," Zeolites, 9, 341-345 (1989).

Patents:

Method and adsorbent to separate mixtures of enantiomers
Authors:
Ozgur Karahan, Juliusz Warzywoda, Michael P. Manning, Albert Sacco Jr.
Description: This invention is related to the generation of a chiral stationary phase. The chiral stationary phase obtained by the process of this invention is useful to resolve mixtures of enantiomers (chiral separation) by adsorption.
Expected Issuance: 2005

Method of Making Titanosilicate ETS-4 suitable for quantum wire applications
Authors: Bilge Yilmaz, Juliusz Warzywoda, Michael P. Manning, Albert Sacco, Jr
Description: This invention relates to methods for preparing crystalline titanosilicate molecular sieve ETS-4 with predictably and precisely controlled characteristics and properties. The ETS-4 product obtained by this invention can be utilized as quantum wires due to its modified characteristics. Utilizing this invention ETS-4 product can be tailored for the specific needs of any application.
Expected Issuance: 2005

Professional Affiliations:

International Zeolite Association

Phi Lambda Upsilon

Hobbies:

Hiking, tennis, literature, travel